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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2010 Volume 20, Issue 1, Pages 33–35 (Mi mendc2982)

This article is cited in 12 papers

Influence of 5,15-bis(4’-tert-butylphenyl)-2,8,12,18-tetra(n-butyl)-3,7,13,17-tetramethylporphyrin of FeIII on methyl methacrylate and styrene radical polymerization

Yu. B. Monakova, R. M. Islamovaa, I. A. Ionovaa, S. A. Syrbub, T. A. Ageevab, O. I. Koifmanb

a Ufa Institute of Chemistry, Ufa Federal Research Centre of the Russian Academy of Sciences, Ufa, Russian Federation
b Ivanovo State University of Chemistry and Technology, Ivanovo, Russian Federation

Abstract: Controlled radical polymerization of methyl methacrylate and styrene initiated by azobisisobutironitrile or benzoyl peroxide in the presence of a chlorine-containing complex of FeIII with 5,15-bis(4-tert-butylphenyl)-2,8,12,18-tetra(n-butyl)-3,7,13,17-tetramethylporphyrin was investigated.

Keywords: Controlled radical polymerization, metal complexes of porphyrins, azo-bis-isobutironitrile, benzoyl peroxide, methyl methacrylate.

Language: English

DOI: 10.1016/j.mencom.2010.01.013



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