Influence of 5,15-bis(4’-tert-butylphenyl)-2,8,12,18-tetra(n-butyl)-3,7,13,17-tetramethylporphyrin of FeIII on methyl methacrylate and styrene radical polymerization
Abstract:
Controlled radical polymerization of methyl methacrylate and styrene initiated by azobisisobutironitrile or benzoyl peroxide in the presence of a chlorine-containing complex of FeIII with 5,15-bis(4’-tert-butylphenyl)-2,8,12,18-tetra(n-butyl)-3,7,13,17-tetramethylporphyrin was investigated.
Keywords:Controlled radical polymerization, metal complexes of porphyrins, azo-bis-isobutironitrile, benzoyl peroxide, methyl methacrylate.