S. A. Amelichev, V. V. Popov, L. S. Konstantinova, S. P. Golova, V. V. Novikov, E. D. Lubuzh, L. V. Mikhalchenko, V. P. Gul'tyai, O. A. Rakitin, “Identification of the [1,3]dithiolo[4,5-<i>d</i>]dithiazolyl radical”, Mendeleev Commun., 2010, Volume 20, Issue 2,Pages <nobr>80

This article is cited in 5 papers

Identification of the [1,3]dithiolo[4,5-d]dithiazolyl radical

S. A. Amelichev^a, V. V. Popov^a, L. S. Konstantinova^a, S. P. Golova^a, V. V. Novikov^b, E. D. Lubuzh^a, L. V. Mikhalchenko^a, V. P. Gul'tyai^a, O. A. Rakitin^a

^a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: The synthesis of 5-oxo[1,3]dithiolo[4,5-d][1,3,2]dithiazol-1-ium chloride 1a from easily available zink chelate, TEA[Zn(DMIT)₂], has been developed; salt 1a has been converted to the first representative of [1,3]dithiolo[4,5-d]dithiazolyl radical, which was identified by EPR and CV data.

Keywords: 1,3,2-dithiazolyl radicals, synthesis, 1,3,2-dithiazolium salts, reduction, cyclic voltammetry, EPR spectroscopy.

Language: English

DOI: 10.1016/j.mencom.2010.03.005