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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2023 Volume 33, Issue 1, Pages 37–40 (Mi mendc300)

This article is cited in 3 papers

Communications

Halogen-substituted salicylhydroximate copper(II) metallacrowns: from synthesis and structures to novel applications

M. A. Katkovaa, G. S. Zabrodinaa, R. V. Rumyantceva, G. Yu. Zhigulina, M. S. Muravyevaab, M. P. Shuryginaac, S. A. Chesnokova, S. Yu. Ketkova

a G.A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhnii Novgorod, Russian Federation
b Privolzhsky Research Medical University, Nizhny Novgorod, Russian Federation
c Alexander Butlerov Institute of Chemistry, Kazan Federal University, Kazan, Russian Federation

Abstract: New halogen-substituted salicylhydroximate copper(II) metallacrowns were synthesized from Cu(OAc)2 and the corresponding salicylhydroxamic acids. Their molecular structure was determined by single crystal X-ray diffraction. The compounds obtained represent the first members of the metallacrown family that can be used as components of active initiators for the photopolymerization of oligo-carbonate dimethacrylate by visible light.

Keywords: copper(ii) metallacrowns, organohalogen compounds, salicylhydroxamic acids, X-ray structure, DFT calculations, photo- polymerization of dimethacrylate.

Language: English

DOI: 10.1016/j.mencom.2023.01.011



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