M. A. Katkova, G. S. Zabrodina, R. V. Rumyantcev, G. Yu. Zhigulin, M. S. Muravyeva, M. P. Shurygina, S. A. Chesnokov, S. Yu. Ketkov, “Halogen-substituted salicylhydroximate copper(II) metallacrowns: from synthesis and structures to novel applications”, Mendeleev Commun., 2023, Volume 33, Issue 1,Pages <nobr>37

This article is cited in 3 papers

Communications

Halogen-substituted salicylhydroximate copper(II) metallacrowns: from synthesis and structures to novel applications

M. A. Katkova^a, G. S. Zabrodina^a, R. V. Rumyantcev^a, G. Yu. Zhigulin^a, M. S. Muravyeva^ab, M. P. Shurygina^ac, S. A. Chesnokov^a, S. Yu. Ketkov^a

^a G.A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhnii Novgorod, Russian Federation
^b Privolzhsky Research Medical University, Nizhny Novgorod, Russian Federation
^c Alexander Butlerov Institute of Chemistry, Kazan Federal University, Kazan, Russian Federation

Abstract: New halogen-substituted salicylhydroximate copper(II) metallacrowns were synthesized from Cu(OAc)₂ and the corresponding salicylhydroxamic acids. Their molecular structure was determined by single crystal X-ray diffraction. The compounds obtained represent the first members of the metallacrown family that can be used as components of active initiators for the photopolymerization of oligo-carbonate dimethacrylate by visible light.

Keywords: copper(ii) metallacrowns, organohalogen compounds, salicylhydroxamic acids, X-ray structure, DFT calculations, photo- polymerization of dimethacrylate.

Language: English

DOI: 10.1016/j.mencom.2023.01.011

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