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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2010 Volume 20, Issue 3, Pages 145–147 (Mi mendc3018)

This article is cited in 2 papers

Alteration of the course of the Michaelis–Arbuzov reaction in imidazolium ionic liquids

E. V. Matveeva, V. A. Kozlov, I. L. Odinets

A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: Room-temperature imidazolium ionic liquids [Rmim][X] (X=Br, BF4, NTf2) as a reaction medium change the reaction course of phosphorus(III) acid esters with primary alkyl halides, aryl bromides, and propargyl bromide to afford hydrophosphoryl compounds, products of oxidation of the starting phosphorus substrates, and 2,3-bis(phosphoryl)prop-1-enes, respectively.

Language: English

DOI: 10.1016/j.mencom.2010.05.007



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