Abstract:
Studies of N,N-pentamethylene- and N,N-oxydiethylene-N’,N’-pentamethylenethiocarbamoylsulfenamide zinc(II) complexes by UV and NMR spectroscopy and X-ray diffraction showed the ligand coordination to the metal in a bidentate–chelate manner through the thionic sulfur atom and sulfenamide nitrogen atom with formation of five-membered metallacycle.