V. A. Miluykov, I. A. Bezkishko, O. G. Sinyashin, P. Lönnecke, E. Hey-Hawkins, “3,4,5-Triphenyl-1,2-diphosphacyclopentadienyl copper(I) complexes: synthesis and molecular structure”, Mendeleev Commun., 2010, Volume 20, Issue 4,Pages <nobr>195

This article is cited in 7 papers

3,4,5-Triphenyl-1,2-diphosphacyclopentadienyl copper(I) complexes: synthesis and molecular structure

V. A. Miluykov^a, I. A. Bezkishko^a, O. G. Sinyashin^a, P. Lönnecke^b, E. Hey-Hawkins^b

^a A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Kazan, Russian Federation
^b Institut für Anorganische Chemie, Universität Leipzig, Leipzig, Germany

Abstract: Sodium 3,4,5-triphenyl-1,2-diphosphacyclopentadienide or 1-trimethylstannyl-3,4,5-triphenyl-1,2-diphosphacyclopenta-2,4-diene reacts with [Cu(Cl)L] [L=PPh₃, P(cyclo-C₅H₉)₃] to form dimeric complexes with three-coordinate copper atoms.

Keywords: phosphacyclopentadienide, copper, complexes.

Language: English

DOI: 10.1016/j.mencom.2010.06.003