D. A. Tyurin, E. S. Shiryaeva, V. I. Feldman, “Structure and photochemical rearrangement of the 3,3-dimethylbut-1-yne radical cation”, Mendeleev Commun., 2010, Volume 20, Issue 4,Pages <nobr>205

This article is cited in 4 papers

Structure and photochemical rearrangement of the 3,3-dimethylbut-1-yne radical cation

D. A. Tyurin^a, E. S. Shiryaeva^a, V. I. Feldman^ab

^a Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
^b N.S. Enikolopov Institute of Synthetic Polymeric Materials, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: The structure of the 3,3-dimethylbut-1-yne radical cation and its unusual photochemical rearrangement to the trimethylallene radical cation have been characterized by low-temperature matrix EPR spectroscopy and DFT calculations.

Keywords: radical cations, EPR, low-temperature matrices.

Language: English

DOI: 10.1016/j.mencom.2010.06.007