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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2010 Volume 20, Issue 4, Pages 220–222 (Mi mendc3045)

This article is cited in 2 papers

Chelation-assisted pentafluorophenylation of oximes

V. V. Levina, R. T. Gritsenkoab, A. D. Dilmana, P. A. Belyakova, A. A. Korlyukovc, D. E. Arkhipovbc, M. I. Struchkovaa, V. A. Tartakovskya

a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
b Higher Chemical College of the Russian Academy of Sciences, D.I. Mendeleev University of Chemical Technology of Russia, Moscow, Russian Federation
c A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: The pentafluorophenylation of salicylic aldehyde O-R-oximes is accomplished by their preliminary transformation into difluoroboryl chelate complexes, which react with (C6F5)3SiF in the presence of sodium acetate.

Language: English

DOI: 10.1016/j.mencom.2010.06.013



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