I. L. Dalinger, I. A. Vatsadze, T. K. Shkineva, G. P. Popova, S. A. Shevelev, “The specific reactivity of 3,4,5-trinitro-1<i>H</i>-pyrazole”, Mendeleev Commun., 2010, Volume 20, Issue 5,Pages <nobr>253

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The specific reactivity of 3,4,5-trinitro-1H-pyrazole

I. L. Dalinger, I. A. Vatsadze, T. K. Shkineva, G. P. Popova, S. A. Shevelev

N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: Nitration of 3,5-dinitropyrazole with HNO3–H2SO4 mixture gives 3,4,5-trinitro-1H-pyrazole, which in reaction with ammonia, amines or thiols under mild conditions undergoes regioselective nucleophilic substitution of the 4-positioned nitro group.

Language: English

DOI: 10.1016/j.mencom.2010.09.003

	*Supplementary materials:*
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