D. A. Loginov, A. A. Pronin, Z. A. Starikova, P. V. Petrovskii, A. R. Kudinov, “Photochemical arene exchange in the (borole)cobalt complex [(η-C4H4BOH)Co(η-C6H6)]BF4”, Mendeleev Commun., 2010, Volume 20, Issue 5,Pages 271

This article is cited in 12 papers

Photochemical arene exchange in the (borole)cobalt complex [(η-C₄H₄BOH)Co(η-C₆H₆)]BF₄

D. A. Loginov, A. A. Pronin, Z. A. Starikova, P. V. Petrovskii, A. R. Kudinov

A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: Visible-light irradiation of the cation [(η-C₄H₄BOH)Co(η-C₆H₆)]⁺ in the presence of alkyl-substituted benzenes in CH₂Cl₂ results in arene exchange giving [(η-C₄H₄BOH)Co(η-C₆R₆)]⁺ (C₆R₆= toluene, p-xylene or mesitylene); the structure of [(η-C₄H₄BOH)Co(η-mesitylene)]BF₄ was confirmed by X-ray diffraction.

Language: English

DOI: 10.1016/j.mencom.2010.09.010