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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2010 Volume 20, Issue 5, Pages 271–272 (Mi mendc3062)

This article is cited in 12 papers

Photochemical arene exchange in the (borole)cobalt complex [(η-C4H4BOH)Co(η-C6H6)]BF4

D. A. Loginov, A. A. Pronin, Z. A. Starikova, P. V. Petrovskii, A. R. Kudinov

A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: Visible-light irradiation of the cation [(η-C4H4BOH)Co(η-C6H6)]+ in the presence of alkyl-substituted benzenes in CH2Cl2 results in arene exchange giving [(η-C4H4BOH)Co(η-C6R6)]+ (C6R6= toluene, p-xylene or mesitylene); the structure of [(η-C4H4BOH)Co(η-mesitylene)]BF4 was confirmed by X-ray diffraction.

Language: English

DOI: 10.1016/j.mencom.2010.09.010



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