A. G. Shipov, A. A. Korlyukov, D. E. Arkhipov, E. P. Kramarova, V. V. Negrebetsky, S. Yu. Bylikin, A. A. Nikolin, H. Fan, M. Yu. Antipin, Yu. I. Baukov, “Synthesis and structural characterization of the anionic chelates of hypercoordinate silicon, the derivatives of glycolic and tartaric acids”, Mendeleev Commun., 2010, Volume 20, Issue 5,Pages <nobr>273

This article is cited in 5 papers

Synthesis and structural characterization of the anionic chelates of hypercoordinate silicon, the derivatives of glycolic and tartaric acids

A. G. Shipov^a, A. A. Korlyukov^b, D. E. Arkhipov^b, E. P. Kramarova^c, V. V. Negrebetsky^c, S. Yu. Bylikin^c, A. A. Nikolin^c, H. Fan^c, M. Yu. Antipin^b, Yu. I. Baukov^c

^a N.I. Pirogov Russian National Research Medical University, Moscow, Russian Federation
^b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
^c Russian State Medical University, Moscow, Russian Federation

Abstract: Reactions of 1-(trimethoxysilylmethyl)-2-piperidone with glycolic and (R,R)-tartaric acids in the presence of dicyclohexylamine afford cation–anionic complexes with different coordination states of the Si atoms.

Keywords: pentacoordinated silicon, hexacoordinated silicon, anionic complexes, X-ray structure.

Language: English

DOI: 10.1016/j.mencom.2010.09.011

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