N. K. Gusarova, S. F. Malysheva, A. V. Artem'ev, N. A. Belogorlova, A. I. Albanov, B. A. Trofimov, “Reaction of phosphine with allylbenzene in the KOH–DMSO system: regioselective synthesis of (1-phenylprop-2-yl)phosphine and bis(1-phenylprop-2-yl)phosphine”, Mendeleev Commun., 2010, Volume 20, Issue 5,Pages <nobr>275

This article is cited in 4 papers

Reaction of phosphine with allylbenzene in the KOH–DMSO system: regioselective synthesis of (1-phenylprop-2-yl)phosphine and bis(1-phenylprop-2-yl)phosphine

N. K. Gusarova, S. F. Malysheva, A. V. Artem'ev, N. A. Belogorlova, A. I. Albanov, B. A. Trofimov

A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russian Federation

Abstract: Phosphine reacts with allylbenzene in the KOH–DMSO system (90–110°C, 2–2.5h, atmospheric pressure) to afford Markovnikov adducts, (1-phenylprop-2-yl)phosphine and/or bis(1-phenylprop-2-yl)phosphine in 53–80% yields.

Language: English

DOI: 10.1016/j.mencom.2010.09.012