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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2010 Volume 20, Issue 6, Pages 343–345 (Mi mendc3087)

This article is cited in 16 papers

Photochemical synthesis and interconversions of organocopper(II) complexes in low-temperature matrices: an EPR study

A. V. Lobanova, E. N. Golubevab, M. Ya. Melnikovb

a M.V. Lomonosov Moscow State University, Moscow, Russian Federation
b Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation

Abstract: The EPR spectra of new paramagnetic copper(II) complexes generated by the photolysis of [(RH)4N+]2[CuIICl4]2– were identified,and a quantitative study of the dynamics of photochemical product formation and interconversions at 77–110K was carried out.

Keywords: Tetraalkylammonium tetrachlorocuprates, organocopper(II) complexes, EPR.

Language: English

DOI: 10.1016/j.mencom.2010.11.014



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