N. A. Chernysheva, S. V. Yas'ko, N. K. Gusarova, A. A. Tatarinova, L. V. Klyba, B. A. Trofimov, “Radical addition of secondary phosphine sulfides and selenides to vinyl tellurides”, Mendeleev Commun., 2010, Volume 20, Issue 6,Pages <nobr>346

This article is cited in 10 papers

Radical addition of secondary phosphine sulfides and selenides to vinyl tellurides

N. A. Chernysheva, S. V. Yas'ko, N. K. Gusarova, A. A. Tatarinova, L. V. Klyba, B. A. Trofimov

A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russian Federation

Abstract: The regiospecific addition of secondary phosphine sulfide and phosphine selenide to alkyl vinyl tellurides proceeds under radical initiation (AIBN, 65–70°C, 2.5–3.5h) to afford the anti-Markovnikov adducts, (2-alkyltellanylethyl)phosphine chalcogenides, in 86–99% yields.

Language: English

DOI: 10.1016/j.mencom.2010.11.015