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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2009 Volume 19, Issue 1, Pages 37–38 (Mi mendc3110)

This article is cited in 15 papers

New phosphorus ylides in reactions of tertiary phosphines with phosphorylated quinone methide

Yu. V. Bakhtiyarovaa, M. S. Bondara, V. V. Andriyashina, O. N. Kataevab, I. V. Galkinaa, V. I. Galkina

a Alexander Butlerov Institute of Chemistry, Kazan Federal University, Kazan, Russian Federation
b A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Kazan, Russian Federation

Abstract: A series of new phosphonium ylides have been synthesized by the reaction of dimethyl-(3,5-di-tert-butyl-4-oxo-2,5-cyclohexadienylidene)methylphosphonate with tertiary phosphines, the structure of dimethoxyphosphoryl-3,5-di-tert-butyl-4-hydroxyphenylmethylidene triphenylphosphorane has been confirmed by X-ray single crystal diffraction.

Keywords: quinine methides, tertiary phosphines, ylides, betaines, X-ray single crystal diffraction.

Language: English

DOI: 10.1016/j.mencom.2009.01.015



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