A. V. Borisov, V. K. Osmanov, G. N. Borisova, Zh. V. Matsulevich, G. K. Fukin, “Synthesis of condensed sulfur- and nitrogen-containing heterocycles <i>via</i> polar cycloaddition of hetarene sulfenyl chlorides to a C–C multiple bond”, Mendeleev Commun., 2009, Volume 19, Issue 1,Pages <nobr>49

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Synthesis of condensed sulfur- and nitrogen-containing heterocycles via polar cycloaddition of hetarene sulfenyl chlorides to a C–C multiple bond

A. V. Borisov^a, V. K. Osmanov^a, G. N. Borisova^a, Zh. V. Matsulevich^a, G. K. Fukin^b

^a R.E. Alekseev Nizhnii Novgorod State Technical University, Nizhnii Novgorod, Russian Federation
^b G.A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhnii Novgorod, Russian Federation

Abstract: The reactions of HetSCl, where Het = 4,6-dimethyl-2-pyrimidyl, 3-methoxycarbonyl-2-pyridyl, 1,3-benzothiazol-2-yl and 8-quinolyl, with a carbon–carbon multiple bond in the LiClO₄–MeNO₂ system lead to the formation of products of polar cycloaddition of sulfur-containing electrophile with ring closure by the nitrogen atom of the HetS fragment.

Language: English

DOI: 10.1016/j.mencom.2009.01.020