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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2009 Volume 19, Issue 2, Pages 96–98 (Mi mendc3131)

This article is cited in 5 papers

Kinetics of the 1,3-dinitrobenzene dianion protonation with 1-butyl-3-methylimidazolium cations

L. V. Mikhalchenko, A. S. Mendkovich, M. A. Syroeshkin, V. P. Gul'tyai

N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: To estimate the applicability of 1-butyl-3-methylimidazolium (bmim+) cation as an electrolyte for electrochemistry, the rate constant of the 1,3-dinitrobenzene dianion protonation with bmim+ in DMF has been measured by cyclic voltammetry and chronoamperometry as 100±30 and 82±6 dm3 mol–1 s–1 and compared with the values for phenol.

Keywords: 1,3-dinitrobenzene, electroreduction, 1-butyl-3-methylimidazolium tetrafluoroborate, chronoamperometry, cyclic voltammetry.

Language: English

DOI: 10.1016/j.mencom.2009.03.015



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