O. S. Kukovinets, T. I. Zvereva, N. N. Kabal'nova, V. G. Kasradze, E. V. Salimova, L. R. Khalitova, M. I. Abdullin, L. V. Spirikhin, “Ozonolysis of verbenone in aprotic solvents”, Mendeleev Commun., 2009, Volume 19, Issue 2,Pages <nobr>106

This article is cited in 9 papers

Ozonolysis of verbenone in aprotic solvents

O. S. Kukovinets^a, T. I. Zvereva^a, N. N. Kabal'nova^b, V. G. Kasradze^b, E. V. Salimova^b, L. R. Khalitova^b, M. I. Abdullin^a, L. V. Spirikhin^b

^a Department of Chemical Technology, Bashkirian State University, Ufa, Russian Federation
^b Ufa Institute of Chemistry, Ufa Federal Research Centre of the Russian Academy of Sciences, Ufa, Russian Federation

Abstract: The ozonolysis of verbenone in methylene chloride and acetonitrile at –60 and 0°C proceeds with cleavage of the double bond and neighbouring σ-bond to give (1R,3S)-acetyl-2,2-dimethylcyclobutane carboxylic acid. The mechanism of the reaction has been proposed.

Keywords: ozonolysis of verbenone, (1R, 3S)-3-acetyl-2,2-dimethylcyclobutane carboxylic acid, mechanism of ozonolysis, aprotonic solvents.

Language: English

DOI: 10.1016/j.mencom.2009.03.019