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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2009 Volume 19, Issue 3, Pages 141–143 (Mi mendc3147)

This article is cited in 9 papers

Hydroxyl-directed trifluoromethylation of hydrazones

A. D. Dilmana, V. V. Levina, P. A. Belyakova, A. A. Korlyukovb, M. I. Struchkovaa, V. A. Tartakovskya

a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: The trifluoromethylation of hydrazones derived from salicyl aldehydes and N-aminopiperidine and N-aminomorpholine through the generation of chelate difluoroboron complexes, which subsequently interact with Me3SiCF3 in the presence of sodium acetate, has been developed.

Language: English

DOI: 10.1016/j.mencom.2009.05.009



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