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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2009 Volume 19, Issue 3, Pages 147–148 (Mi mendc3149)

This article is cited in 16 papers

Hydrolysis product of the [Na(15-crown-5)] salt of the [1,2,5]thiadiazolo[3,4-c][1,2,5]thiadiazolidyl radical anion

E. Lorka, R. Mewsa, A. V. Zibarevbc

a Institut für Anorganische und Physikalische Chemie, Universität Bremen, Bremen, Germany
b N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation
c Department of Physics, Novosibirsk State University, Novosibirsk, Russian Federation

Abstract: At ambient temperature, interaction of the solid radical anion salt [Na(15-crown-5)][C2N4S2] with water vapour unexpectedly leads to the trithionate salt [Na(15-crown-5)]2[S(SO3)2], whose coordination pattern is very different from the previously studied trithionate salts.

Language: English

DOI: 10.1016/j.mencom.2009.05.011



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