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JOURNALS // Mendeleev Communications // Archive
Mendeleev Commun., 2009 Volume 19, Issue 3, Pages 165–166 (Mi mendc3157)
This article is cited in 16 papers

Molybdenum-mediated imido-transfer reaction of N-sulfinylamines with dimethylformamide

A. A. Zhizhin, D. N. Zarubin, N. A. Ustynyuk

A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: Dimethylformamide undergoes molybdenum-mediated metathetical imido-deoxygenation with ortho-substituted by donor atoms N-sulfinylanilines affording formamidines; N-sulfinylamines undergo molybdenum-mediated condensation into sulfurdiimines.

Keywords: metathesis, imido-deoxygenation, molybdenum, N-sulfinylamines, formamidines, sulfurdiimines.

Language: English

DOI: 10.1016/j.mencom.2009.05.019


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