D. G. Yakhvarov, R. M. Kagirov, I. Kh. Rizvanov, V. I. Morozov, O. G. Sinyashin, “New aspects of the electroreduction of palladium dichloride complex with 1,2-bis(diphenylphosphino)ethane”, Mendeleev Commun., 2009, Volume 19, Issue 4,Pages <nobr>190

This article is cited in 4 papers

New aspects of the electroreduction of palladium dichloride complex with 1,2-bis(diphenylphosphino)ethane

D. G. Yakhvarov, R. M. Kagirov, I. Kh. Rizvanov, V. I. Morozov, O. G. Sinyashin

A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Kazan, Russian Federation

Abstract: The electrochemical reduction of a mono-chelate palladium dichloride complex with 1,2-bis(diphenylphosphino)ethane (dppe) in DMF results in formation of highly reactive mono-chelate palladium(0) complex, which reacts with initial complex by reaction of the ligand abstraction forming stable bischelate complex [Pd⁰(dppe)₂] and palladium dichloride.

Language: English

DOI: 10.1016/j.mencom.2009.07.005