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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2009 Volume 19, Issue 4, Pages 214–216 (Mi mendc3174)

This article is cited in 19 papers

Z/E(C=C)-isomerization of coumarin enamines induced by organic solvents

V. F. Traven'a, I. V. Ivanova, V. S. Lebedeva, B. G. Milevskiia, T. A. Chibisovaa, N. P. Solov'evab, V. I. Polshakovb, O. N. Kazhevac, G. G. Alexandrovd, O. A. Dyachenkoc

a D.Mendeleev University of Chemical Technology of Russia, Moscow, Russian Federation
b Center for Drug Chemistry, Moscow, Russian Federation
c Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation
d N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: Imines of 3-formyl-4-hydroxycoumarin have been found to exist in E- and Z-ketoenamine forms in a crystal state and undergo Z/E-isomerization around the C=C bond in organic solvents (e.g., CHCl3).

Language: English

DOI: 10.1016/j.mencom.2009.07.014



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