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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2009 Volume 19, Issue 6, Pages 314–316 (Mi mendc3210)

Reliable rate constant determination for heterogeneous electron transfer: CrEDTA

A. S. Kotkina, A. G. Krivenkoa, G. N. Botukhovab, G. A. Tsirlinab

a Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation
b Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation

Abstract: Pulse and steady-state photoemission techniques are applied to determine the heterogeneous rate constant of CrEDTA– reduction on liquid mercury. The resulting value (too high for polarographic determination and available earlier only for amalgamated gold) is important for experimental verification of various predictions of the electron transfer theory.

Language: English

DOI: 10.1016/j.mencom.2009.11.006



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