K. N. Shavrin, V. D. Gvozdev, S. V. Yurov, O. M. Nefedov, “Unusual reactions of 1-(alk-1-ynyl)-1-chlorocyclopropanes with lithium monoalkylamides”, Mendeleev Commun., 2008, Volume 18, Issue 1,Pages <nobr>16

This article is cited in 10 papers

Unusual reactions of 1-(alk-1-ynyl)-1-chlorocyclopropanes with lithium monoalkylamides

K. N. Shavrin^a, V. D. Gvozdev^a, S. V. Yurov^b, O. M. Nefedov^a

^a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b D.Mendeleev University of Chemical Technology of Russia, Moscow, Russian Federation

Abstract: Depending on the substituent at the triple bond, the reaction of 1-(alk-1-ynyl)-1-chlorocyclopropanes 1 with lithium monoalkylamides in THF gives hitherto unknown conjugated iminocyclopropenes 2 or 4-substituted 1,1-dimethylbuta-1,2-dienes 3 in up to 60% yields.

Language: English

DOI: 10.1016/j.mencom.2008.01.007