M. Yu. Dvorko, T. E. Glotova, A. I. Albanov, N. N. Chipanina, O. N. Kazheva, G. V. Shilov, O. A. Dyachenko, “Chemo- and stereodirectivity of the reaction of thiocarbohydrazide with 1-acetyl-2-phenylacetylene: synthesis and structure of bis(1-methyl-3-phenyl-2-propynylidene)carbonothioic dihydrazide”, Mendeleev Commun., 2008, Volume 18, Issue 1,Pages <nobr>48

This article is cited in 3 papers

Chemo- and stereodirectivity of the reaction of thiocarbohydrazide with 1-acetyl-2-phenylacetylene: synthesis and structure of bis(1-methyl-3-phenyl-2-propynylidene)carbonothioic dihydrazide

M. Yu. Dvorko^a, T. E. Glotova^a, A. I. Albanov^a, N. N. Chipanina^a, O. N. Kazheva^b, G. V. Shilov^b, O. A. Dyachenko^b

^a A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russian Federation
^b Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation

Abstract: 1-Acetyl-2-phenylacetylene reacts with thiocarbohydrazide under mild conditions to afford exclusively N2-(Z-s-trans), N3-(Z-s-cis)- bis(1-methyl-3-phenyl-2-propynylidene)carbonothioic dihydrazide in high yield (up to 92%); the structure of the compound has been confirmed by IR and NMR spectroscopy and X-ray analysis.

Language: English

DOI: 10.1016/j.mencom.2008.01.018