K. B. Nuzhdin, V. I. Feldman, A. V. Kobzarenko, “Delocalized methoxyacetone radical cation: structure and reactivity”, Mendeleev Commun., 2008, Volume 18, Issue 2,Pages <nobr>69

This article is cited in 8 papers

Delocalized methoxyacetone radical cation: structure and reactivity

K. B. Nuzhdin^a, V. I. Feldman^ab, A. V. Kobzarenko^a

^a Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
^b N.S. Enikolopov Institute of Synthetic Polymeric Materials, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: The radical cation (RC) of methoxyacetone exhibits a delocalization of spin density between two oxygen atoms with considerable spin population on methylene hydrogen atoms, which results in the selective deprotonation of this RC.

Keywords: radical cation, EPR, methoxyacetone.

Language: English

DOI: 10.1016/j.mencom.2008.03.003