R. N. Naumov, A. A. Karasik, K. B. Kanunnikov, A. V. Kozlov, Sh. K. Latypov, K. V. Domasevitch, E. Hey-Hawkins, O. G. Sinyashin, “Synthesis of a chiral macrocyclic tetraphosphine –1,9-di-R,R(and S,S)-α-methylbenzyl-3,7,11,15-tetramesityl-1,9-diaza-3,7,11,15-(RSSR)-tetraphosphacyclohexadecane”, Mendeleev Commun., 2008, Volume 18, Issue 2,Pages 80

This article is cited in 22 papers

Synthesis of a chiral macrocyclic tetraphosphine –1,9-di-R,R(and S,S)-α-methylbenzyl-3,7,11,15-tetramesityl-1,9-diaza-3,7,11,15-(RSSR)-tetraphosphacyclohexadecane

R. N. Naumov^a, A. A. Karasik^a, K. B. Kanunnikov^a, A. V. Kozlov^a, Sh. K. Latypov^a, K. V. Domasevitch^b, E. Hey-Hawkins^c, O. G. Sinyashin^a

^a A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Kazan, Russian Federation
^b T.G. Shevchenko Kiev National University, Kiev, Ukraine
^c Institut für Anorganische Chemie, Universität Leipzig, Leipzig, Germany

Abstract: Two enantiomers of the title compound containing six chiral atoms have been synthesised via stereoselective covalent self-assembly of two diphosphinopropane, four formaldehyde and two primary amine molecules.

Keywords: Chiral macrocyclic phosphine, self-assembly, stereoselectivity.

Language: English

DOI: 10.1016/j.mencom.2008.03.008