R. G. Kostyanovsky, A. F. Pozharskii, Yu. V. Nelyubina, K. A. Lyssenko, G. K. Kadorkina, A. V. Degtyarev, O. G. Nabiev, I. I. Chervin, “Absolute configuration of a chiral proton sponge”, Mendeleev Commun., 2008, Volume 18, Issue 2,Pages <nobr>86–87</nobr>

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Mendeleev Commun., 2008 Volume 18, Issue 2, Pages 86–87 (Mi mendc3257)

This article is cited in 3 papers

Absolute configuration of a chiral proton sponge

R. G. Kostyanovsky^a, A. F. Pozharskii^b, Yu. V. Nelyubina^c, K. A. Lyssenko^c, G. K. Kadorkina^a, A. V. Degtyarev^b, O. G. Nabiev^a, I. I. Chervin^a

^a N.N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, Moscow, Russian Federation
^b Department of Chemistry, Southern Federal University, Rostov-on-Don, Russian Federation
^c A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: By the spontaneous resolution of racemic compound 1,8-bis(dimethylamino)-2-(α-hydroxy-α-phenylethyl)naphthalene (±)-1, enantiomer (–)-1 was obtained; its treatment with C₅H₅N·HBr resulted in the formation of proton sponge (–)-2; the absolute configurations of (R)-(–)-2 and, as a consequence, (R)-(–)-1 were determined by XRD analysis.

Language: English

DOI: 10.1016/j.mencom.2008.03.011

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