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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2008 Volume 18, Issue 3, Pages 126–127 (Mi mendc3270)

This article is cited in 5 papers

Incorporation of gas molecules into the frameworks of clathrate hydrates of ion-exchange resins in tetraalkylammonium form

S. S. Skiba, I. S. Terekhova, E. G. Larionov, A. Yu. Manakov

A.V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation

Abstract: The decomposition temperatures of the hydrates of carboxylic cationites in tetraisoamylammonium (TiAA) and tetrabutylammonium (TBA) forms increase considerably in the presence of hydrogen (at 50MPa, ΔT≈6.5°C for TiAA and 5.0°C for TBA; at 150MPa, ΔT≈8.1°C for TiAA and 6.2°C for TBA).

Language: English

DOI: 10.1016/j.mencom.2008.05.004



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