A. Yu. Verat, V. G. Shtyrlin, B. I. Khairutdinov, F. D. Sokolov, L. N. Yamalieva, D. B. Krivolapov, N. G. Zabirov, I. A. Litvinov, V. V. Klochkov, “Dynamic behaviour of the complex [Ni{PhC(S)NP(O)(OPri)2-O,S}2-{PhC(S)NHP(O)(OPri)2-O}2] in deuterotrichloromethane”, Mendeleev Commun., 2008, Volume 18, Issue 3,Pages <nobr>150

This article is cited in 11 papers

Dynamic behaviour of the complex [Ni{PhC(S)NP(O)(OPri)2-O,S}2-{PhC(S)NHP(O)(OPri)2-O}2] in deuterotrichloromethane

A. Yu. Verat^a, V. G. Shtyrlin^a, B. I. Khairutdinov^a, F. D. Sokolov^a, L. N. Yamalieva^a, D. B. Krivolapov^b, N. G. Zabirov^a, I. A. Litvinov^b, V. V. Klochkov^a

^a Alexander Butlerov Institute of Chemistry, Kazan Federal University, Kazan, Russian Federation
^b A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Kazan, Russian Federation

Abstract: The title complex has been studied by ¹H and ³¹P NMR spectroscopy and found to undergo reversible dissociation of its neutral ligands and interconversion of its neutral and anionic ligands; the kinetic parameters of these processes and the crystal structure of the complex were determined; a new ligand exchange mechanism with unusual high spin–low spin transition during the ligand dissociation was suggested.

Language: English

DOI: 10.1016/j.mencom.2008.05.013