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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2008 Volume 18, Issue 4, Pages 205–206 (Mi mendc3298)

This article is cited in 2 papers

Oxidative transformation of the dicobalthexacarbonyl complexes of γ-hydroxyalkynes

I. K. Sagamanovaa, V. V. Tumanovb, W. A. Smitb

a Higher Chemical College of the Russian Academy of Sciences, D.I. Mendeleev University of Chemical Technology of Russia, Moscow, Russian Federation
b N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: The title compounds were found to undergo an oxidative cyclization–hydrocarbonylation reaction under the standard conditions of decomplexation by treatment with cerium(IV) ammonium nitrate.

Keywords: oxidative alkyne hydroxycarbonylation, dicobalthexacarbonyl complexed alkynes, cerium(IV) ammonium nitrate.

Language: English

DOI: 10.1016/j.mencom.2008.07.012



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