E. V. Starodubtseva, V. I. Sokolov, V. V. Bashilov, Yu. N. Novikov, E. V. Martynova, M. G. Vinogradov, O. V. Turova, “Fullerene complexes with palladium and rhodium as catalysts for acetylenic bond hydrogenation”, Mendeleev Commun., 2008, Volume 18, Issue 4,Pages <nobr>209–210</nobr>

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Mendeleev Commun., 2008 Volume 18, Issue 4, Pages 209–210 (Mi mendc3300)

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Fullerene complexes with palladium and rhodium as catalysts for acetylenic bond hydrogenation

E. V. Starodubtseva^a, V. I. Sokolov^b, V. V. Bashilov^b, Yu. N. Novikov^b, E. V. Martynova^b, M. G. Vinogradov^a, O. V. Turova^a

^a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: The catalytic activity of the fullerene complexes (C₆₀)Pd(PPh₃)₂, (C₇₀)Pd(PPh₃)₂, (C₆₀)Pd[(+)-DIOP] and (C₆₀)RhH(CO)(PPh₃)₂ in the hydrogenation of acetylenic bond has been studied using diphenylacetylene as a model substrate.

Language: English

DOI: 10.1016/j.mencom.2008.07.014

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