A. V. Stepanov, E. A. Mistryukov, “Aluminium–isopropanol reduction of <i>tert</i>-nitronitriles: an unusual structure of the reduction products”, Mendeleev Commun., 2008, Volume 18, Issue 4,Pages <nobr>215

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Aluminium–isopropanol reduction of tert-nitronitriles: an unusual structure of the reduction products

A. V. Stepanov, E. A. Mistryukov

N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: The reduction of γ-nitronitriles with aluminium–isopropanol results in a cyclic product, strongly O-nucleophilic iminonitronium, which is resistant to further reduction.

Language: English

DOI: 10.1016/j.mencom.2008.07.017