A. S. Vinogradov, V. I. Krasnov, V. E. Platonov, “Unusual interaction of perfluoroaromatic organozinc compounds with benzoyl chloride and DMF”, Mendeleev Commun., 2008, Volume 18, Issue 4,Pages <nobr>227

This article is cited in 7 papers

Unusual interaction of perfluoroaromatic organozinc compounds with benzoyl chloride and DMF

A. S. Vinogradov, V. I. Krasnov, V. E. Platonov

N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation

Abstract: The organozinc compounds obtained from chloropentafluorobenzene and octafluorotoluene in reactions with benzoyl chloride and DMF form N,N-dimethylbis(perfluoroaryl)methylamines; the addition of CuCl changes the direction of reaction towards the formation of corresponding polyfluoroaromatic ketones.

Language: English

DOI: 10.1016/j.mencom.2008.07.022