D. V. Kazakov, F. E. Safarov, V. P. Kazakov, R. Schmidt, “A new bright chemiluminescent reaction: interaction of acetone with solid potassium peroxymonosulfate in the complex of europium nitrate”, Mendeleev Commun., 2008, Volume 18, Issue 5,Pages <nobr>249

This article is cited in 2 papers

A new bright chemiluminescent reaction: interaction of acetone with solid potassium peroxymonosulfate in the complex of europium nitrate

D. V. Kazakov^a, F. E. Safarov^a, V. P. Kazakov^a, R. Schmidt^b

^a Ufa Institute of Chemistry, Ufa Federal Research Centre of the Russian Academy of Sciences, Ufa, Russian Federation
^b Institut für Physikalische und Theoretische Chemie, Johann Wolfgang Goethe-Universität Frankfurt, Frankfurt am Main, Germany

Abstract: The interaction of acetone with a mixture of potassium peroxymonosulfate and europium nitrate hexahydrate powders at 90°C is accompanied by chemiluminescence due to the formation of excited Eu3+; dioxirane is proposed to be a key intermediate responsible for the chemiluminescence observed.

Keywords: chemiluminescence, lanthanides, dioxiranes, singlet oxygen.

Language: English

DOI: 10.1016/j.mencom.2008.09.006

	*Supplementary materials:*
		Supplementary_data_1.pdf	87.7 Kb