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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2008 Volume 18, Issue 6, Pages 309–311 (Mi mendc3338)

This article is cited in 16 papers

o-Iodoxybenzoic acid in dimethylformamide as a convenient reagent for the oxidation of alcohols to aldehydes and ketones

M. A. Lapitskaya, L. L. Vasiljeva, K. K. Pivnitsky

N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: DMF dissolves o-iodoxybenzoic acid (up to 0.1mol dm−3) and, therefore, is a solvent of choice for the reactions with o-iodoxybenzoic acid simplifying significantly a product isolation procedure due to a higher volatility. The reaction rate and selectivity of the oxidation of alcohols to corresponding carbonyl compounds with o-iodoxybenzoic acid in DMF are close to those in DMSO.

Language: English

DOI: 10.1016/j.mencom.2008.11.007



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