B. A. Trofimov, S. F. Vasilevskii, N. K. Gusarova, S. F. Malysheva, D. S. Baranov, V. I. Mamatyuk, Yu. V. Gatilov, “Complex of tris(<i>Z</i>-styryl)phosphine with PdCl<sub>2</sub> as a new catalyst for the Sonogashira reaction”, Mendeleev Commun., 2008, Volume 18, Issue 6,Pages <nobr>318–319</nobr>

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Mendeleev Commun., 2008 Volume 18, Issue 6, Pages 318–319 (Mi mendc3341)

This article is cited in 12 papers

Complex of tris(Z-styryl)phosphine with PdCl₂ as a new catalyst for the Sonogashira reaction

B. A. Trofimov^a, S. F. Vasilevskii^b, N. K. Gusarova^a, S. F. Malysheva^a, D. S. Baranov^b, V. I. Mamatyuk^c, Yu. V. Gatilov^c

^a A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russian Federation
^b V.V. Voevodsky Institute of Chemical Kinetics and Combustion, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation
^c N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation

Abstract: The complex [(Z-PhCH=CH)₃P]₂PdCl₂ synthesized from tris(Z-styryl)phosphine and PdCl₂ (DMF, 90 °C, 15min, yield 50%) is an active catalyst in the Sonogashira reaction (coupling between 1-ethynyl-4-nitrobenzene and 1-iodoanthra-9,10-quinone) and its activity is comparable with that of the complex [Ph₃P]₂PdCl₂, the most common catalyst for this type of reactions.

Language: English

DOI: 10.1016/j.mencom.2008.11.010

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