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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2008 Volume 18, Issue 6, Pages 342–344 (Mi mendc3352)

This article is cited in 4 papers

Viscoelasticity of poly(vinylpyridinium chloride)/sodium dodecylsulfate adsorption films at the air–water interface

A. G. Bykova, Sh.-Y. Lina, G. Logliob, R. Millerc, B. A. Noskovd

a Department of Chemical Engineering, National Taiwan University, Taipei, Taiwan
b Dipartimento di Chimica, Universita di Firenze, Florence, Italy
c MPI für Kolloid- und Grenzflächenforschung, Golm, Germany
d Department of Chemistry, St. Petersburg State University, St. Petersburg, Russian Federation

Abstract: Measurements of the dynamic elasticity of an adsorption film of poly(vinylpyridinium chloride)/sodium dodecylsulfate (PVP/SDS) complexes indicate a structure transition in the film when the surfactant concentration approaches the concentration of PVP monomers and show that the rate of relaxation processes in polyelectrolyte/surfactant adsorption films is determined by the properties of the polymer chain.

Keywords: polyelectrolyte/surfactant complexes, aqueous solutions, surface properties, surface tension, surface viscoelasticity.

Language: English

DOI: 10.1016/j.mencom.2008.11.021



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