M. U. Agaeva, B. N. Mankaev, V. I. Filippenko, V. A. Serova, M. P. Egorov, S. S. Karlov, “A convenient synthesis of N,N',N''-trisubstituted diethylenetriamines”, Mendeleev Commun., 2023, Volume 33, Issue 2,Pages 157

This article is cited in 2 papers

Communications

A convenient synthesis of N,N',N''-trisubstituted diethylenetriamines

M. U. Agaeva^ab, B. N. Mankaev^ab, V. I. Filippenko^b, V. A. Serova^ab, M. P. Egorov^a, S. S. Karlov^ab

^a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation

Abstract: N,N',N''-Trisubstituted diethylenetriamines (1,4,7-triaza-heptanes) were synthesized by reduction of the relevantly substituted 2,2'-iminodiacetiamides which, in turn, were accessed from cheap reactants by the methods depending on their nature. The triamines thus obtained may be promising ligands for metal catalysts.

Keywords: diethylenetriamines, ligands, microwave-assisted synthesis, polyamines, carboxamides, reduction, amidation.

Language: English

DOI: 10.1016/j.mencom.2023.02.003

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