M. E. Minyaev, K. A. Lyssenko, P. A. Belyakov, M. Yu. Antipin, D. M. Roitershtein, “Synthesis and structure of ytterbium(II) complexes with the tetraphenylethylene dianion”, Mendeleev Commun., 2007, Volume 17, Issue 2,Pages <nobr>102–104</nobr>

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Mendeleev Commun., 2007 Volume 17, Issue 2, Pages 102–104 (Mi mendc3392)

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Synthesis and structure of ytterbium(II) complexes with the tetraphenylethylene dianion

M. E. Minyaev^ab, K. A. Lyssenko^c, P. A. Belyakov^d, M. Yu. Antipin^c, D. M. Roitershtein^ab

^a L. Ya. Karpov Institute of Physical Chemistry, Moscow, Russian Federation
^b Department of Chemistry and Biology, Moscow City Pedagogical University, Moscow, Russian Federation
^c A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
^d N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: Ytterbium(II) and ytterbium(III) halides react with disodium or dipotassium tetraphenylethenide to form the complex dianion [Yb(Ph₂CCPh₂)₂]^2–, which demonstrates bis-η³-coordination of the tetraphenylethylene dianions to the Yb²⁺ cation in a solid state.

Language: English

DOI: 10.1016/j.mencom.2007.03.017

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