P. A. Troshin, A. B. Kornev, A. S. Peregudov, S. M. Peregudova, R. N. Lyubovskaya, “Benzylamine imines as versatile precursors to azomethine and nitrile ylides in the [2 + 3] cycloaddition reactions with [60]fullerene”, Mendeleev Commun., 2007, Volume 17, Issue 2,Pages <nobr>116

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Benzylamine imines as versatile precursors to azomethine and nitrile ylides in the [2 + 3] cycloaddition reactions with [60]fullerene

P. A. Troshin^a, A. B. Kornev^a, A. S. Peregudov^b, S. M. Peregudova^b, R. N. Lyubovskaya^a

^a Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation
^b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: Pyrrolidino- and pyrrolinofullerenes were prepared using readily available benzylamine imines as reagents; the cyclic voltammetry measurements revealed that the C=N double bond mediates an electronic communication between the fullerene π-system and a substituent attached to the sp² carbon of the pyrroline ring.

Language: English

DOI: 10.1016/j.mencom.2007.03.022

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