H. J. Frohn, V. V. Bardin, “Distinct reactivities of cis- and trans-RFCF=CFBF2 towards XeF2 and the first synthesis of a [trans-RFCF=CFXe]+ salt”, Mendeleev Commun., 2007, Volume 17, Issue 3,Pages 137

This article is cited in 4 papers

Distinct reactivities of cis- and trans-R_FCF=CFBF₂ towards XeF₂ and the first synthesis of a [trans-R_FCF=CFXe]⁺ salt

H. J. Frohn^a, V. V. Bardin^b

^a Department of Chemistry, Institute of Inorganic Chemistry, University of Duisburg-Essen, Duisburg, Germany
^b N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation

Abstract: The competitive reaction of C₄F₉CF=CFBF₂ (cis : trans = 1.2:1) with XeF₂ demonstrated for the first time a remarkably lower reaction rate of the trans isomer with respect to the cis isomer in the xenodeborylation reaction (formation of the [C₄F₉CF=CFXe]⁺ cation with a cis : trans ratio of 2.5 to 4:1) and allowed us to develop reaction conditions for the syntheses of [trans-C₄F₉CF=CFXe]⁺ salts.

Language: English

DOI: 10.1016/j.mencom.2007.05.001