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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2007 Volume 17, Issue 3, Pages 139–141 (Mi mendc3404)

This article is cited in 3 papers

Stereoselectivity of allylboron–acetylene condensation with crotylic boranes: synthesis of 4-methyl-1-boraadamantane derivatives

S. Yu. Erdyakova, S. V. Stefanyuka, A. V. Ignatenkoa, M. E. Gurskiia, Yu. N. Bubnovab

a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: The determining influence of the nature of a crotylborating reagent on the stereoresult of the allylboron–acetylene condensation with crotylic boranes has been revealed and applied to the synthesis of 4-methyl-1-boraadamantane derivatives.

Language: English

DOI: 10.1016/j.mencom.2007.05.002



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