B. A. Trofimov, S. F. Malysheva, N. K. Gusarova, N. A. Belogorlova, S. F. Vasilevskii, V. B. Kobychev, B. G. Sukhov, I. A. Ushakov, “Free-radical addition of phosphine sulfides to aryl and hetaryl acetylenes: unprecedented stereoselectivity”, Mendeleev Commun., 2007, Volume 17, Issue 3,Pages <nobr>181–182</nobr>

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Mendeleev Commun., 2007 Volume 17, Issue 3, Pages 181–182 (Mi mendc3419)

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Free-radical addition of phosphine sulfides to aryl and hetaryl acetylenes: unprecedented stereoselectivity

B. A. Trofimov^a, S. F. Malysheva^a, N. K. Gusarova^a, N. A. Belogorlova^a, S. F. Vasilevskii^b, V. B. Kobychev^a, B. G. Sukhov^a, I. A. Ushakov^a

^a A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russian Federation
^b V.V. Voevodsky Institute of Chemical Kinetics and Combustion, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation

Abstract: Secondary phosphine sulfides react stereo- and regioselectively with aryl and hetaryl acetylenes in the presence of radical initiators (AIBN, 60–65 °C) in the anti-Markovnikov mode giving Z-isomers of the corresponding monoadducts in high yields.

Language: English

DOI: 10.1016/j.mencom.2007.05.017

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