V. E. Pushkarev, M. O. Breusova, S. E. Nefedov, L. G. Tomilova, “Synthesis and structure of europium(III) double- and triple-decker complexes with 2,3,9,10,16,17,23,24-octabutylphthalocyanine”, Mendeleev Commun., 2007, Volume 17, Issue 4,Pages <nobr>220

This article is cited in 6 papers

Synthesis and structure of europium(III) double- and triple-decker complexes with 2,3,9,10,16,17,23,24-octabutylphthalocyanine

V. E. Pushkarev^a, M. O. Breusova^a, S. E. Nefedov^b, L. G. Tomilova^a

^a Institute of Physiologically Active Compounds, Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation
^b N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: The reaction of 4,5-dibutylphthalodinitrile with Eu(acac)₃·3H₂O at 130 °C results in sandwich-type bis[2,3,9,10,16,17,23,24- octabutylphthalocyaninato]europium(III) 1 and the reaction of free 2,3,9,10,16,17,23,24-octabutylphthalocyanine with Eu(acac)₃·3H₂O at 196 °C gives tris[2,3,9,10,16,17,23,24-octabutylphthalocyaninato]dieuropium(III) 2. Structures of compounds 1 and 2 have been determined using X-ray diffraction analysis, electronic and NMR spectroscopy and mass spectrometry.

Language: English

DOI: 10.1016/j.mencom.2007.06.012