F. D. Sokolov, S. V. Baranov, N. G. Zabirov, D. B. Krivolapov, I. A. Litvinov, B. I. Khairutdinov, R. A. Cherkasov, “Unusual structure of an N-phosphoryl-N’-isopropylthiourea chelate with the nickel(II) cation”, Mendeleev Commun., 2007, Volume 17, Issue 4,Pages 222

This article is cited in 17 papers

Unusual structure of an N-phosphoryl-N’-isopropylthiourea chelate with the nickel(II) cation

F. D. Sokolov^a, S. V. Baranov^a, N. G. Zabirov^a, D. B. Krivolapov^b, I. A. Litvinov^b, B. I. Khairutdinov^a, R. A. Cherkasov^a

^a Alexander Butlerov Institute of Chemistry, Kazan Federal University, Kazan, Russian Federation
^b A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Kazan, Russian Federation

Abstract: The reaction of the potassium salt of N-phosphorylated thiourea PrⁱN'HC(S)NHP(O)(OPrⁱ)₂ (HL) with the Ni^II cation leads to the complex [NiL₂(HL)₂]; according to X-ray analysis, two neutral HL molecules are coordinated in the second sphere of the planar 1,3-N,S-chelate [NiL₂] via (HL) PNH···O=P (NiL₂) hydrogen bonds.

Language: English

DOI: 10.1016/j.mencom.2007.06.013