Yu. G. Gololobov, O. A. Linchenko, P. V. Petrovskii, V. N. Khrustalev, I. A. Garbuzova, “Dual reactivity of the phosphonium zwitterion formed by the reaction of triisopropylphosphine with ethyl 2-cyanoacrylate toward 2,4-dinitro- and 2,4,6-trinitrofluorobenzenes”, Mendeleev Commun., 2007, Volume 17, Issue 4,Pages <nobr>232

This article is cited in 5 papers

Dual reactivity of the phosphonium zwitterion formed by the reaction of triisopropylphosphine with ethyl 2-cyanoacrylate toward 2,4-dinitro- and 2,4,6-trinitrofluorobenzenes

Yu. G. Gololobov, O. A. Linchenko, P. V. Petrovskii, V. N. Khrustalev, I. A. Garbuzova

A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: A phosphonium zwitterion formed by the reaction of triisopropylphosphine with ethyl 2-cyanoacrylate possesses a dual reactivity: while this ion reacts with 2,4-dinitrofluorobenzene as a C-nucleophile, it reacts with 2,4,6-trinitrofluorobenzene as an N-nucleophile.

Language: English

DOI: 10.1016/j.mencom.2007.06.017