RUS  ENG
Full version
JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2007 Volume 17, Issue 4, Pages 237–238 (Mi mendc3443)

This article is cited in 10 papers

A peculiar vinylation of 1-substituted imidazoles with, α,β-acetylenic γ-hydroxyacid nitriles

B. A. Trofimov, L. V. Andriyankova, A. G. Mal'kina, K. V. Belyaeva, L. P. Nikitina, L. V. Baikalova

A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russian Federation

Abstract: 1-Substituted imidazoles react smoothly with α,β-acetylenic γ-hydroxyacid nitriles to give 1-imidazolyl-2-alkenenitriles in 37–56% yields, thus representing an unknown type of the imidazole ring vinylation accompanied by the replacement of the substituent at the nitrogen atom.

Language: English

DOI: 10.1016/j.mencom.2007.06.019



© Steklov Math. Inst. of RAS, 2025