L. K. Kibardina, M. A. Pudovik, V. A. Alfonsov, O. N. Kataeva, “Synthesis of enantiopure 1,3,4-thiazaphospholes”, Mendeleev Commun., 2007, Volume 17, Issue 6,Pages <nobr>323

This article is cited in 1 paper

Synthesis of enantiopure 1,3,4-thiazaphospholes

L. K. Kibardina, M. A. Pudovik, V. A. Alfonsov, O. N. Kataeva

A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Kazan, Russian Federation

Abstract: Racemic and (R)-(+)-N-trimethylsilyl-(1-phenyl)ethylamines stereoselectively react with O-phenylchloromethylisothiocyanatothiophosphonate to give a diastereomeric mixture of separable 1,3,4-thiazaphospholes; racemic thiazaphosphole crystallises as a conglomerate.

Keywords: Thiazaphosphole, Racemic and R-(+)-N-trimethylsilyl-(1-phenyl)ethylamines, Cyclization reaction, diastereoselectivity.

Language: English

DOI: 10.1016/j.mencom.2007.11.007